Non-RRKM decomposition of chemically activated radicals: Reaction of fluorine atoms with tetraallyl germanium

✍ Scribed by Patricia J. Rogers; Jodye I. Selco; F.S. Rowland

• Publisher: Elsevier Science
• Year: 1983
• Tongue: English
• Weight: 411 KB
• Volume: 97
• Category: Article
• ISSN: 0009-2614
• DOI: 10.1016/0009-2614(83)80014-1

✦ Synopsis

I-rrroms rcacr wirh :aeous (CH2= CHCH&Gc IO produce CHz= CHF ~hrou& dicsocijlion of tlw (CH, = CHCH: GeCH~CHI-'CH~ radical. The rapid decomposirion is artriburcd to non-RRK?l bclxwior xirh cxciiarion cncrsy lar& confined to the CH~C'Hl'CH~ side group. The central atoms mass effect found in linear sewn-atom tmjccrory cdcula~ions hi\ not yet appeared in (CH~=ClICH2)4hl \cith the replacement of Sn by Cc.