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Non-RRKM decomposition in a chemical activation system: thermal atomic fluorine plus tetraallyl tin

โœ Scribed by Patricia Rogers; Derek C. Montague; Joan P. Frank; Stanley C. Tyler; F.S. Rowland

Publisher
Elsevier Science
Year
1982
Tongue
English
Weight
355 KB
Volume
89
Category
Article
ISSN
0009-2614

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Non-RRKM decomposition of chemically act
Non-RRKM decomposition of chemically activated radicals: Reaction of fluorine atoms with tetraallyl germanium
โœ Patricia J. Rogers; Jodye I. Selco; F.S. Rowland ๐Ÿ“‚ Article ๐Ÿ“… 1983 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 411 KB

I-rrroms rcacr wirh :aeous (CH2= CHCH&Gc IO produce CHz= CHF ~hrou& dicsocijlion of tlw (CH, = CHCH: GeCH~CHI-'CH~ radical. The rapid decomposirion is artriburcd to non-RRK?l bclxwior xirh cxciiarion cncrsy lar& confined to the CH~C'Hl'CH~ side group. The central atoms mass effect found in linear se