✦ LIBER ✦

Decomposition mechanism and kinetics of n-butylsilane

✍ Scribed by Sawrey, B. A.; O'Neal, H. E.; Ring, Moray A.

Book ID: 125981536
Publisher: American Chemical Society
Year: 1987
Tongue: English
Weight: 626 KB
Volume: 6
Category: Article
ISSN: 0276-7333
DOI: 10.1021/om00147a007

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Kinetics and mechanism of the decomposit

Kinetics and mechanism of the decomposition of N,N-dihalopeptides

✍ William D. Stanbro; Michael J. Lenkevich 📂 Article 📅 1985 🏛 John Wiley and Sons 🌐 English ⚖ 547 KB

The tripeptide alanylalanylalanine reacts with either HOCl or HOBr to form a N, Ndihalopeptide. These compounds decompose to the N-halo-N'-(a-iminoket0)peptides plus halide ion. The rate constants for these reactions in 0.4-M NaCl were determined to be (PH 6.7) k4 = 1.06 x 1015e 18,400'RT min-' (PH

The kinetics and mechanism of the decomp

The kinetics and mechanism of the decomposition of N-chloroleucine

✍ Juan M. Antelo; Florencio Arce; Julia Franco; Pilar Rodriguez; Angel Varela 📂 Article 📅 1988 🏛 John Wiley and Sons 🌐 English ⚖ 334 KB 👁 2 views

At 298 K the rate constant for the decomposition of N-chloroleucine has the constant value 3.20 >: lo-\* s-' over the range pH 5-12, increases with increasing acidity at pH < 5, and increases with pH a t pH > 12. A mechanism is put forward which explains these results.

Kinetics and mechanism of the silane dec

Kinetics and mechanism of the silane decomposition

✍ C. G. Newman; H. E. O'neal; M. A. Ring; F. Leska; N. Shipley 📂 Article 📅 1979 🏛 John Wiley and Sons 🌐 English ⚖ 871 KB

The homogeneous gas-phase decomposition kinetics of silane has been investigated using the single-pulse shock tube comparative rate technique (T = 1035-1184°K, P ~d = 4000 Torr). The initial reaction of the decomposition SiH4 ! + SiHz + H2 is a unimolecular process in its pressure fall-off regime w

Kinetics and Mechanism of the Thermal De

Kinetics and Mechanism of the Thermal Decomposition of Si3N4

✍ H. DEAN BATHA; E. DOW WHITNEY 📂 Article 📅 1973 🏛 John Wiley and Sons 🌐 English ⚖ 570 KB

Kinetics and mechanism of the shock indu

Kinetics and mechanism of the shock induced thermal decomposition of n-propylsilane

✍ B. A. Sawrey; H. E. O'Neal; M. A. Ring; D. Coffey Jr. 📂 Article 📅 1984 🏛 John Wiley and Sons 🌐 English ⚖ 727 KB

The kinetics and mechanism of the thermal decomposition of n-propylsilane have been studied by the single pulse shock tube-comparative rate technique a t pressures around 4700 torr between 1095-1240 K. The primary dissociation processes are 1,l and 1,2 H, elimination with &,,, = 0.75 and &,,\* = 0.2

Kinetics and mechanism of the decomposit

Kinetics and mechanism of the decomposition of N-bromoalcoholamines in aqueous solution

✍ J. M. Antelo; F. Arce; J. Franco; M. J. Forneas; M. E. Sanchez; A. Varela 📂 Article 📅 1986 🏛 John Wiley and Sons 🌐 English ⚖ 421 KB 👁 2 views

The decomposition reactions of N-bromodiethanolamine. N-bromoethylethanolamine, and AT-bromomethylethanolamine in aqueous solution have been studied kineticall) under various experimental conditions. The results support a proposed reaction mechanism in which the rate controlling step is assumed to b