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Cyclocholates with 12-Oxo and 7,12-Oxo Groups

✍ Scribed by Hongwu Gao; Jerry Ray Dias


Publisher
John Wiley and Sons
Year
1998
Tongue
English
Weight
464 KB
Volume
1998
Category
Article
ISSN
1434-193X

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✦ Synopsis


Syntheses of bile acid cyclooligomers with 12-and 7,12-oxo groups (6a؊d, 7a؊c, 8a؊b) by the Yamaguchi method are described. Cyclotrimerization is the principal reaction route for these cholic acid systems. Conversion of 7-and 12-hydroxy groups in cholic acid (1a؊b) to oxo groups (4a؊c,


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