The crystal structure of the title compound, C 12 H 13 NO 3 S, is stabilized by intermolecular N-HÁ Á ÁO hydrogen bonds, which are formed between the NH groups and the sulfoxide O atoms.
Ethyl 7-oxo-7H-indeno[2′,1′:3,4]pyrrolo[2,1-a]quinoline-12-carboxylate
✍ Scribed by Liu, Yun ;Li, Zhe ;Shen, Yong-Miao ;Zhang, Yan ;Xu, Jian-Hua
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 102 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
In the title compound, C 22 H 15 NO 3 , the quinoline system is essentially planar, and the mean plane of the indenone ring system is almost coplanar with the quinoline group. The crystal structure is stabilized by inter-and intramolecular C-HÁ Á ÁO hydrogen-bonding interactions.
📜 SIMILAR VOLUMES
The regio-and stereochemistry of the title compound, C 18 H 18 O 3 , has been established by X-ray analysis. The bond lengths and angles are normal.
The title compound, C 14 H 13 NO 5 , exhibits a resonance-assisted hydrogen bond O-HÁ Á ÁO C [2.505 (4) A ˚], which leads to a lengthening of the carbonyl C O bond, a shortening of the C-OH bond and delocalization of the electron density within the dihydropyridine ring.
The title compound, C 15 H 17 N 3 O 3 S, a potent new plant elicitor, was synthesized by reaction between 1,2,3-benzothiadiazole-7carbonyl chloride and ethyl piperidine-4-carboxylate. The piperidine ring adopts a chair conformation. Weak intermolecular C-HÁ Á ÁO hydrogen bonds stabilize the crystal