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The syntheses and complexing properties of oxo-12-crown-3 and oxo-18-crown-5

✍ Scribed by Geoffrey D. Beresford; J. Fraser Stoddart

Publisher
Elsevier Science
Year
1980
Tongue
French
Weight
310 KB
Volume
21
Category
Article
ISSN
0040-4039

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✦ Synopsis

Derivatives of 12-crown-4

and 18-crown-6 in which one of the ethereal occlJgens is replaced by a CO group have been synthesised and their cornplexing abilities towards both metal and organic cations have been assessed. VariabLe temperature lH decotq,Zed 13C n.m.r. spectmswpy reveals the presence of anisometric species in solution when a I:1 complex is formed between 0x0-ld-cronr-5 and ISI+hChWeNH3+ClO~-.

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