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Cyclic substituted dithiocarbamates as ligands. Vanadium(III)and oxovanadium(IV, V) complexes

✍ Scribed by Fabrizia Forghieri; Gianni Graziosi; Carlo Preti; Giuseppe Tosi

Publisher: Springer
Year: 1983
Tongue: English
Weight: 539 KB
Volume: 8
Category: Article
ISSN: 0340-4285
DOI: 10.1007/bf00618577

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The preparation of oxovanadium(IV,V) coordination compounds with 2-acetylpyridine-2-furanoylhydrazone (Hapf) is described. [VO(apf)(acac)] was prepared from oxovanadium(IV) diacetylacetonate [VO(acac) 2 ] by reaction with Hapf in methanol or dichloromethane. The complex is paramagnetic and its EPR s