## Abstract The reactions of V^V^O(Oβ__i__Pr)~3~ with [PS3β²]H~3~ and [PS3]H~3~ {[PS3β²]H~3~ = P(C~6~H~3~β5βMeβ2βSH)~3~, [PS3]H~3~ = P(C~6~H~4~β2βSH)~3~} led to the formation of [V^IV^(L)] [L = P2S4β² (1a), P2S4 (1b)], where L was formed by the oxidative coupling of two PS3β² or PS3 ligands by a disulf
β¦ LIBER β¦
Spectroscopic techniques in the study of the nature of metal-ligand bonding in vanadium(III) and oxovanadium(IV,V) para -and metasubstituted benzeneseleninato complexes
β Scribed by Gianni Graziosi; Carlo Preti; Giuseppe Tosi
- Publisher
- Springer
- Year
- 1982
- Tongue
- English
- Weight
- 523 KB
- Volume
- 7
- Category
- Article
- ISSN
- 0340-4285
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The "V-NMR spectroscopic behavior in water of a series of vanadium peroxo complexes was investigated. Monoperoxo vanadium complexes containing bidentate ligands in which the two binding sites are either oxygen atoms (0 f~ 0 ligands) or one oxygen and one nitrogen atom (N n 0 ligands) and diperoxo va