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Alkyl and cyclic substituted thiuram disulphides as ligands. titanium(iv), vanadium(iv), and oxovanadium(iv) complexes

✍ Scribed by Isabel Cuadrado; Moisés Morán

Publisher: Springer
Year: 1986
Tongue: English
Weight: 765 KB
Volume: 11
Category: Article
ISSN: 0340-4285
DOI: 10.1007/bf01225987

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## Abstract The reactions of V^V^O(O‐__i__Pr)~3~ with [PS3′]H~3~ and [PS3]H~3~ {[PS3′]H~3~ = P(C~6~H~3~‐5‐Me‐2‐SH)~3~, [PS3]H~3~ = P(C~6~H~4~‐2‐SH)~3~} led to the formation of [V^IV^(L)] [L = P2S4′ (1a), P2S4 (1b)], where L was formed by the oxidative coupling of two PS3′ or PS3 ligands by a disulf