The Zn center in [bis(3-pyridylacrylato)diaquazinc(II)] n is in a slightly distorted octahedral geometry within a cis-N 2 O 4 donor set. Each tridentate 3-pyridylacrylate ligand links two Zn centers, resulting in the formation of a linear chain.
Crystallographic report: [(1,3-Bis(4-pyridyl)propane)(diaqua)zinc(II)] diperchlorate dihydrate
β Scribed by Seung Hoon Choi; Ji Young Ryu; Jun Yong Lee; Young Chan Myoung; Cheal Kim; Youngmee Kim; Byung Ho Song
- Publisher
- John Wiley and Sons
- Year
- 2004
- Tongue
- English
- Weight
- 78 KB
- Volume
- 18
- Category
- Article
- ISSN
- 0268-2605
- DOI
- 10.1002/aoc.641
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β¦ Synopsis
Abstract
Four ligands of 1,3βbis(4βpyridyl)propane and two water molecules are coordinated to the zinc(II) atom so that the coordination geometry closely resembles a transβN~4~O~2~ octahedral environment. Copyright Β© 2004 John Wiley & Sons, Ltd.
π SIMILAR VOLUMES
The mononuclear structure of Zn(S 2 CN(CH 2 ) 4 ) 2 (4,7-Ph 2 -1,10-phenanthroline) shows the zinc atom in each of the two independent molecules comprising the asymmetric unit to exist in a distorted octahedral geometry defined by an N 2 S 4 donor set.