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Crystallographic report: Polymeric [diaqua bis(3-pyridylacrylato)zinc(II)]

✍ Scribed by Qian Wu; Xue-Feng Huang; Ting Zhou; Yun-Zhi Tang; Ren-Gen Xiong

Publisher
John Wiley and Sons
Year
2005
Tongue
English
Weight
71 KB
Volume
19
Category
Article
ISSN
0268-2605

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✦ Synopsis

The Zn center in [bis(3-pyridylacrylato)diaquazinc(II)] n is in a slightly distorted octahedral geometry within a cis-N 2 O 4 donor set. Each tridentate 3-pyridylacrylate ligand links two Zn centers, resulting in the formation of a linear chain.

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## Abstract Four ligands of 1,3‐bis(4‐pyridyl)propane and two water molecules are coordinated to the zinc(II) atom so that the coordination geometry closely resembles a __trans__‐N~4~O~2~ octahedral environment. Copyright Β© 2004 John Wiley & Sons, Ltd.

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The molecular structure of [Zn(O 2 CC 6 H 4 NO 2 -p) 2 (pyridine) 2 ] exhibits a distorted N 2 O 2 tetrahedral geometry around the zinc atom owing to the presence of monodentate p-nitrobenzoate ligands; the molecule has twofold symmetry.