Crystallographic report: Bis[bis(N,N-diethyldithiocarbamato)zinc(II)] (trans-1,2-bis(4-pyridyl)ethylene)trans-1, 2-bis(4-pyridyl)ethylene lattice adduct
✍ Scribed by Chian Sing Lai; Edward R. T. Tiekink
- Publisher
- John Wiley and Sons
- Year
- 2003
- Tongue
- English
- Weight
- 76 KB
- Volume
- 17
- Category
- Article
- ISSN
- 0268-2605
- DOI
- 10.1002/aoc.420
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📜 SIMILAR VOLUMES
In the dinuclear molecule of [(C 5 H 4 N) 3 N] 2 CdCl 2 CdCl 2 , one cadmium is octahedrally coordinated by a Cl 2 N 4 donor set and the other cadmium is tetrahedrally coordinated by four chlorine atoms. The dinuclear units are connected by π -π interactions to give a two-dimensional network.
## Abstract The structure of the title compound, [Zn~2~(btc)(DMF)~2~]~__n__~ (btc = 1,2,4,5‐benzenetetracarboxylate, DMF = __N__,__N__‐dimethylformamide), shows that the octahedrally and tetrahedrally coordinated zinc atoms (present in the ratio 1:1) are linked by btc ligands to form a three‐dimens