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Crystallographic report: Bis[tris(2-pyridyl)amine]cadmium(II)-di-µ-chloro-dichloro-cadmium(II), [(C5H4N)3N]2CdCl2CdCl2

✍ Scribed by Yongshu Xie; Xueting Liu; Jia Ni; Hui Jiang; Qingliang Liu

Publisher
John Wiley and Sons
Year
2003
Tongue
English
Weight
94 KB
Volume
17
Category
Article
ISSN
0268-2605

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✦ Synopsis

In the dinuclear molecule of [(C 5 H 4 N) 3 N] 2 CdCl 2 CdCl 2 , one cadmium is octahedrally coordinated by a Cl 2 N 4 donor set and the other cadmium is tetrahedrally coordinated by four chlorine atoms. The dinuclear units are connected by π -π interactions to give a two-dimensional network.

📜 SIMILAR VOLUMES

Crystallographic report: Diiodo[tris(2-p
Crystallographic report: Diiodo[tris(2-pyridyl)amine]mercury(II), [(C5H4N)3N]HgI2
✍ Yongshu Xie; Xueting Liu; Jia Ni; Hui Jiang; Qingliang Liu 📂 Article 📅 2003 🏛 John Wiley and Sons 🌐 English ⚖ 68 KB

## Abstract In mononuclear HgI~2~[(C~5~H~4~N)~3~N], mercury is tetrahedrally coordinated by two nitrogen atoms of a tris(2‐pyridyl)amine ligand and two iodides. The coordination moieties are connected by weak intermolecular Hg(II)···I interactions to give a one‐dimensional structure. Copyright © 20