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Crystal structure of oxotitanium(IV) 2,2,6,6-tetramethyl-3,5-heptanedionate

✍ Scribed by N. B. Morozova; A. E. Turgambaeva; I. A. Baidina; V. V. Krysyuk; I. K. Igumenov

Book ID
106427126
Publisher
SP MAIK Nauka/Interperiodica
Year
2005
Tongue
English
Weight
139 KB
Volume
46
Category
Article
ISSN
0022-4766

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## Abstract Palladium bis(2,2,6,6‐tetramethyl‐3,5‐heptanedionate), a structurally well defined __O__‐containing transition metal complex, is reported to be an efficient catalyst for alkoxycarbonylation and aminocarbonylation reactions under milder operating conditions. The system tolerated the carb

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The standard molar enthalpies of formation of crystalline chelates M(thd)3, (M = Sc, Y, La; and thd = 2,2,6,6-tetramethyl-3,5-heptanedionate), determined by reaction-solution calorimetry at T = (298.15 2 0.02) K, were found to be -(2317.83 2 11.7) kJβ€’mol -1 , -(2386.1 2 11.4) kJβ€’mol -1 , and -(2442.