Structure, intramolecular hydrogen bonding, and vibrational spectra of 2,2,6,6-tetramethyl-3,5-heptanedione
β Scribed by M. Vakili; S.F. Tayyari; A.-R. Nekoei; H. Miremad; S. Salemi; R.E. Sammelson
- Book ID
- 108213233
- Publisher
- Elsevier Science
- Year
- 2010
- Tongue
- English
- Weight
- 915 KB
- Volume
- 970
- Category
- Article
- ISSN
- 0022-2860
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## Abstract Palladium bis(2,2,6,6βtetramethylβ3,5βheptanedionate), a structurally well defined __O__βcontaining transition metal complex, is reported to be an efficient catalyst for alkoxycarbonylation and aminocarbonylation reactions under milder operating conditions. The system tolerated the carb
The standard molar enthalpies of formation of crystalline chelates M(thd)3, (M = Sc, Y, La; and thd = 2,2,6,6-tetramethyl-3,5-heptanedionate), determined by reaction-solution calorimetry at T = (298.15 2 0.02) K, were found to be -(2317.83 2 11.7) kJβ’mol -1 , -(2386.1 2 11.4) kJβ’mol -1 , and -(2442.
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