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Palladium bis(2,2,6,6-tetramethyl-3,5-heptanedionate) catalyzed alkoxycarbonylation and aminocarbonylation reactions

✍ Scribed by Pawan J. Tambade; Yogesh P. Patil; Bhalchandra M. Bhanage

Publisher
John Wiley and Sons
Year
2009
Tongue
English
Weight
138 KB
Volume
23
Category
Article
ISSN
0268-2605

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✦ Synopsis

Abstract

Palladium bis(2,2,6,6‐tetramethyl‐3,5‐heptanedionate), a structurally well defined O‐containing transition metal complex, is reported to be an efficient catalyst for alkoxycarbonylation and aminocarbonylation reactions under milder operating conditions. The system tolerated the carbonylative coupling of various aryl halides with phenol/alcohol and amines, providing good to excellent yields of desired products under optimized reaction conditions. Copyright Β© 2009 John Wiley & Sons, Ltd.

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