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4-(Ferrocenylmethyl)-2,2,6,6-tetramethyl-3,5-heptanedione, a non-enolized 1,3-diketone

✍ Scribed by Ferguson, G. ;Glidewell, C. ;Zakaria, C. M.

Book ID: 114511481
Publisher: International Union of Crystallography
Year: 1994
Tongue: English
Weight: 465 KB
Volume: 50
Category: Article
ISSN: 0108-2701
DOI: 10.1107/s0108270194008486

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The standard molar enthalpies of formation of crystalline chelates M(thd)3, (M = Sc, Y, La; and thd = 2,2,6,6-tetramethyl-3,5-heptanedionate), determined by reaction-solution calorimetry at T = (298.15 2 0.02) K, were found to be -(2317.83 2 11.7) kJ•mol -1 , -(2386.1 2 11.4) kJ•mol -1 , and -(2442.