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Crystal and molecular structure of {Ni[(CH3)2C(OH)CH2COCH3]2}{Ni[NCS]4[P(CH2CH2CN)3]2}: a .beta.-hydroxy ketone chelate complex

✍ Scribed by Foxman, Bruce M.; Mazurek, Harry


Book ID
125524552
Publisher
American Chemical Society
Year
1979
Tongue
English
Weight
542 KB
Volume
18
Category
Article
ISSN
0020-1669

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Coordinatedversus Noncoordinated Isocyan
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The triisocyanide ligand CH3C(CH2NC)3 reacts with Cr-acterized by an X-ray structure analysis allowing a direct com-(CO),(THF) depending on the stoichiometry to give the com-parison of the bonding parameters of coordinated and nonplexes CH3C(CH2NC),[CH2NC ~ Cr(C0)5]3-, (x = 1, 2). The coordinated is