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Crystal and molecular structure of bis (μ-chloro)bis[chloro(1,1′-dimethyl-2,2′-diimidazolylsulfide)copper(II)]

✍ Scribed by David A. Baldwin; Jan C. A. Boeyens; Louis Denner; Anthony J. Markwell


Publisher
Springer
Year
1986
Tongue
English
Weight
445 KB
Volume
16
Category
Article
ISSN
1572-8854

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Di-μ-chloro-bis{chloro­[1,2-di­phenyl-2-
✍ Puschmann, Horst ;Batsanov, Andrei S. ;Howard, Judith A. K. ;Soto, Bernardino ;B 📂 Article 📅 2001 🏛 International Union of Crystallography 🌐 English ⚖ 203 KB

The title compound, [Cu 2 Cl 4 (C 20 H 18 N 2 O) 2 ], is a centrosymmetric dimer bridged through the Cl atoms. The bridging Cu 2 Cl 2 unit is planar and each Cu II ion has two different distances to the bridging Cl atom. The Cu II ions are coordinated to three Cl and two N atoms in a squarepyramidal