Synthesis of 1-chloro-1-[15N]nitrosocycl
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Siegfried N. Lodwig; Louis A. Silks III; Clifford J. Unkefer
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Article
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1996
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John Wiley and Sons
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French
⚖ 331 KB
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We have prepared 1 -chloro-l-[15N]nitrosocyclohexane, an electrophillic aminating reagent useful for the stereoselective synthesis of a-[lsN]arnino acids. Treatment of potassium [15N]nitrate with PbO gave potassium [IsNInitrite, which was converted into the intermediate hydroxylamine disulfonate by