Critical Review of Aqueous Solution Reaction Rate Constants for Hydrogen Atoms
โ Scribed by Madden, Keith P.; Mezyk, Stephen P.
- Book ID
- 120226879
- Publisher
- American Institute of Physics
- Year
- 2011
- Tongue
- English
- Weight
- 404 KB
- Volume
- 40
- Category
- Article
- ISSN
- 0047-2689
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
Rate constants have been measured by pulse radiolysis for the reactions of the NO, radical with five cyclic ethers and a series of alcohols. Rate constants ranged from 3.5 x lo4 M-' 5 -l for deuterated methanol to 1.1 x lo7 M-' 5-l for tetrahydrofuran. The rate constants for the reactions of NO3 wit
Laser flash photolysis (at 248 or 308 nm) or aryl iodides in water or water/methanol solutions produces iodine atoms and phenyl radicals. Iodine atoms react rapidly with added I-to form 12-but do not react rapidly with 0 2 ( k I lo7 L mol-l s-l). Iodine atoms oxidize phenols to phenoxyl radicals, wi