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Rate Constants of Some Reactions of H Atoms in Aqueous Solution

✍ Scribed by Navon, Gil; Stein, Gabriel


Book ID
111858620
Publisher
American Chemical Society
Year
1965
Tongue
English
Weight
611 KB
Volume
69
Category
Article
ISSN
0022-3654

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πŸ“œ SIMILAR VOLUMES


Rate constants for reactions of iodine a
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Laser flash photolysis (at 248 or 308 nm) or aryl iodides in water or water/methanol solutions produces iodine atoms and phenyl radicals. Iodine atoms react rapidly with added I-to form 12-but do not react rapidly with 0 2 ( k I lo7 L mol-l s-l). Iodine atoms oxidize phenols to phenoxyl radicals, wi

Rate constants for some reactions of fre
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The kinetics of the acqueous-phase reactions of the free radicals .OH, .Cl,, and SO; . with the halogenated acetates, CHzFCOO-, CHF2COO-, CF3COO-, and with CHzClC00-, CHClzC00-, CC13COOwere investigated. Generally, the reactivity decreases with increasing halogen substitution and is in the order k(.