𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Correction- Chemistry of the Silylamines. I. The Condensation of Monofunctional Silylamines with Monofunctional Silanols

✍ Scribed by Pike, Ronald

Book ID
126205960
Publisher
American Chemical Society
Year
1961
Tongue
English
Weight
141 KB
Volume
26
Category
Article
ISSN
0022-3263

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Chemistry of the silylamines. III. Conde
Chemistry of the silylamines. III. Condensation of silylamines with silylesters
✍ R. M. Pike 📂 Article 📅 2010 🏛 Elsevier Science 🌐 English ⚖ 295 KB

## Abstract The conditions under which a series of trimethylsilylesters of the type magnified image, where R=H, CH~3~, CF~3~, and C~6~H~5~, condense with a number of trimethylsilylamines to form hexamethyl‐disiloxane and an organic amide were investigated. The nature of the R group in the silyl

Chemistry of the silylamines. V. Self-co
Chemistry of the silylamines. V. Self-condensation of R3Si-NH2 type silylamines
✍ R. M. Pike 📂 Article 📅 2010 🏛 Elsevier Science 🌐 English ⚖ 210 KB

## Abstract The rates of self‐condensation of a series of silylamines of the type R~3~SiNH~2~ to form the corresponding disilazanes, (R~3~Si)~2~NH have been measured. The nature of the R groups attached to the silicon atom of the silylamine appreciably affects the rate of condensation. The addition

Chemistry of the silylamines: IV. Conden
Chemistry of the silylamines: IV. Condensation of N,N-diethylamino-trimethylsilane with the triphenylhydroxides of carbon, silicon, and germanium
✍ R. M. Pike 📂 Article 📅 2010 🏛 Elsevier Science 🌐 English ⚖ 181 KB

## Abstract Derivatives of the type (C~6~H~5~)~3~M‐OH, where M  C, Si and Ge, were condensed with __N,N__‐diethylamino‐trimethylsilane in xylene solvent at 50°. The rates of the condensation reaction for this series (C, Si,Ge) were found to be in the ratio of approximately 1 : 3 : 1, respectively.