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Chemistry of the silylamines. III. Condensation of silylamines with silylesters

✍ Scribed by R. M. Pike

Publisher
Elsevier Science
Year
2010
Tongue
English
Weight
295 KB
Volume
80
Category
Article
ISSN
0165-0513

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✦ Synopsis

Abstract

The conditions under which a series of trimethylsilylesters of the type magnified image, where R=H, CH~3~, CF~3~, and C~6~H~5~, condense with a number of trimethylsilylamines to form hexamethyl‐disiloxane and an organic amide were investigated. The nature of the R group in the silylester appreciably affected the relative ease of condensation. Addition of an acid catalyst to the reaction system was observed to increase the relative rate of the reaction.

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