𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Chemistry of the silylamines: IV. Condensation of N,N-diethylamino-trimethylsilane with the triphenylhydroxides of carbon, silicon, and germanium

✍ Scribed by R. M. Pike


Publisher
Elsevier Science
Year
2010
Tongue
English
Weight
181 KB
Volume
80
Category
Article
ISSN
0165-0513

No coin nor oath required. For personal study only.

✦ Synopsis


Abstract

Derivatives of the type (C~6~H~5~)~3~M‐OH, where M ο£Ύ C, Si and Ge, were condensed with N,N‐diethylamino‐trimethylsilane in xylene solvent at 50Β°. The rates of the condensation reaction for this series (C, Si,Ge) were found to be in the ratio of approximately 1 : 3 : 1, respectively.


πŸ“œ SIMILAR VOLUMES


The reaction of isoquinolinium N-phenyli
✍ Robert Temme; Kurt Polborn; Rolf Huisgen πŸ“‚ Article πŸ“… 1998 πŸ› Elsevier Science 🌐 French βš– 549 KB

The cyeloadduct 1 exists in a mobile equilibrium with isoquinolinium N-phenylimide (2) and CS 2. The reaction of 1 with 1-(diethylamino)propyne (3) afforded the 1:1:1 products 4 and $, the latter predominating with higher CS 2 concentration. The NMR spectra and an X-ray analysis of 4 clarified the s

Silicon-29 and carbon-13 NMR studies of
✍ Robin K. Harris; Barry J. Kimber πŸ“‚ Article πŸ“… 1975 πŸ› John Wiley and Sons 🌐 English βš– 555 KB

## Abstract Silicon‐29, carbon‐13 and oxygen‐17 NMR data are reported for the methylethoxysilanes, Me~__n__~Si(OEt)~4βˆ’__n__~ with __n__ = C to 3. The values of ^1^__J__(SiC) vary greatly, in a manner which appears to be inconsistent with an effect of __s__‐character variation alone. The chemical sh