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Chemistry of the silylamines. V. Self-condensation of R3Si-NH2 type silylamines

✍ Scribed by R. M. Pike

Publisher
Elsevier Science
Year
2010
Tongue
English
Weight
210 KB
Volume
81
Category
Article
ISSN
0165-0513

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✦ Synopsis

Abstract

The rates of self‐condensation of a series of silylamines of the type R~3~SiNH~2~ to form the corresponding disilazanes, (R~3~Si)~2~NH have been measured. The nature of the R groups attached to the silicon atom of the silylamine appreciably affects the rate of condensation. The addition of acid catalyst results in an increase in reaction rate. The observed second‐order kinetics indicate a bimolecular type mechanism.

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