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Copper promoted CN and CO bond cross-coupling with phenyl and pyridylboronates

✍ Scribed by Dominic M.T. Chan; Kevin L. Monaco; Renhua Li; Damien Bonne; Charles G. Clark; Patrick Y.S. Lam

Book ID: 104253521
Publisher: Elsevier Science
Year: 2003
Tongue: French
Weight: 180 KB
Volume: 44
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(03)00739-1

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✦ Synopsis

Acyclic and cyclic esters, as well as anhydride (boroxine) of phenylboronic acids are efficient phenylating agents in copper promoted C N and C O bond cross-coupling reactions. The first successful C N cross-coupling of a heterocyclic boronate with heteroarenes, such as indazole, has been demonstrated.

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