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Copper-catalyzed general CN and CO bond cross-coupling with arylboronic acid

✍ Scribed by Patrick Y.S Lam; Guillaume Vincent; Charles G Clark; Sophie Deudon; Prabhakar K Jadhav

Book ID
104230577
Publisher
Elsevier Science
Year
2001
Tongue
French
Weight
144 KB
Volume
42
Category
Article
ISSN
0040-4039

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✦ Synopsis

General catalytic Cu(OAc) 2 /TEMPO in air or Cu(OAc) 2 /O 2 systems for the C N and C O cross-coupling reactions with arylboronic acid have been discovered. N-and O-vinylation have also been demonstrated.

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Copper promoted CN and CO bond cross-c
Copper promoted CN and CO bond cross-coupling with phenyl and pyridylboronates
✍ Dominic M.T. Chan; Kevin L. Monaco; Renhua Li; Damien Bonne; Charles G. Clark; P 📂 Article 📅 2003 🏛 Elsevier Science 🌐 French ⚖ 180 KB

Acyclic and cyclic esters, as well as anhydride (boroxine) of phenylboronic acids are efficient phenylating agents in copper promoted C N and C O bond cross-coupling reactions. The first successful C N cross-coupling of a heterocyclic boronate with heteroarenes, such as indazole, has been demonstrat