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Copper complex protection in the regioselective alkylation of methyl 3,5-dioxohexanoate. Preparation of 3-alkyl derivatives of 4-hydroxy-6-methyl-2-pyrone

✍ Scribed by Jordi Cervello; Jorge Marquet; Marcial Moreno-Mañas


Book ID
111714403
Publisher
Elsevier Science
Year
1987
Tongue
French
Weight
120 KB
Volume
28
Category
Article
ISSN
0040-4039

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Copper protection in the palladium catal
✍ Jorge Marquet; Marcial Moreno-Mañas; María Prat 📂 Article 📅 1989 🏛 Elsevier Science 🌐 French ⚖ 228 KB

Bellaterra. 08193~Barcelona. Spain. Sumnary.-Regioselective allylation of the model polyketide system methyl 3,5\_dioxohexanoate at the C-2 position can be accomplished even with secondary and tertiary radicals by palladium catalyzed allylation of its copper complex, la. Initial results indicate th