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Coping with substituent effects in divinylcyclopropyl diazene rearrangements

✍ Scribed by Georgia Law Carroll; Roy Harrison; James B. Gerken; R.Daniel Little

Book ID
104253093
Publisher
Elsevier Science
Year
2003
Tongue
French
Weight
229 KB
Volume
44
Category
Article
ISSN
0040-4039

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The activation parameters [βˆ†G (200 K), βˆ†H , and βˆ†S ] for compounds, together with those for related compounds previously reported in the literature, show that conjugating the degenerate Cope rearrangements of barbaralane (1a) and several semibullvalenes (3a, 7a, 8a), and for those of a subsituents (