Coping with Substituent Effects in Divinylcyclopropyl Diazene Rearrangements.
β Scribed by Georgia Law Carroll; Roy Harrison; James B. Gerken; R. Daniel Little
- Publisher
- John Wiley and Sons
- Year
- 2003
- Weight
- 55 KB
- Volume
- 34
- Category
- Article
- ISSN
- 0931-7597
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Two possible types of competing [1,3] rearrangements of hydroxy and formyl (donor and acceptor) groups in specific positions have also been considered. On the basis of these divinylcyclopropane derivatives and of the hetero-analogous compounds vinylcyclopropanecarbaldehyde and vinylcyclo-calculation
## Abstract The effect on electrophilic activity of substituents located __para__, __ortho__, and __meta__ to the nitro group of nitrobenzenes was determined by using vicarious nucleophilic substitution of hydrogen (VNS) with the carbanion of chloromethyl phenyl sulfone (**1**) as the model process