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Coordination of CO to the Alkaline Earth Metallocene [(Me5C5)2Ca]

✍ Scribed by Dipl.-Chem. Peter Selg; Prof. Dr. Hans H. Brintzinger; Prof. Dr. Richard A. Andersen; Dr. István T. Horváth


Publisher
John Wiley and Sons
Year
1995
Tongue
English
Weight
352 KB
Volume
34
Category
Article
ISSN
0044-8249

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Synthesis and Structure of [(C5Me5)2M2Se
✍ Prof. Dr. Henri Brunner; Walter Meier; Dr. Joachim Wachter; Dr. Bernd Nuber; Pro 📂 Article 📅 1986 🏛 John Wiley and Sons 🌐 English ⚖ 245 KB 👁 1 views

65% 13 16 Scheme2. Reactionsof 1 ( X ' , X 2 = O ; a ) , 8 ( X ' , X ' = N -N H -T s ; b ) , 9 ( X ' , X'=N-NNa-Ts; c, d), and 10 ( X , = H , X2=Me--S0,; f). a) Al2O3. b) MeLi, EtzO, 0°C. c) 125°C. d) hv, THF, 20°C. e) Preparative gas chromatography, Carbowax, 160°C. f) KOtBu.