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Controlled ring-opening polymerization of cyclic esters with phosphoric acid as catalysts

✍ Scribed by Xi Zhou, Liangzhi Hong


Book ID
120795543
Publisher
Springer
Year
2013
Weight
545 KB
Volume
291
Category
Article
ISSN
0340-255X

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Ring-opening polymerization of cyclic ca
✍ Jyuhou Matsuo; Shinji Nakano; Fumio Sanda; Takeshi Endo πŸ“‚ Article πŸ“… 1998 πŸ› John Wiley and Sons 🌐 English βš– 180 KB πŸ‘ 2 views

Ring-opening reactions of 1,3-dioxepan-2-one (1) and 1,3-dioxan-2-one (2) with several alcohols were examined. The reactions proceeded without trifluoroacetic acid (TFA) in low conversions, while they proceeded smoothly with TFA to afford the ring-opened adducts and oligomers. Ring-opening polymeriz