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Organocatalytic Ring-Opening Polymerization of Cyclic Esters Mediated by Highly Active Bifunctional Iminophosphorane Catalysts

✍ Scribed by Goldys, Anna M.; Dixon, Darren J.


Book ID
121497212
Publisher
American Chemical Society
Year
2014
Tongue
English
Weight
521 KB
Volume
47
Category
Article
ISSN
0024-9297

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Ring-opening polymerization of various c
✍ Naruhito Iwasa; Michiya Fujiki; Kotohiro Nomura πŸ“‚ Article πŸ“… 2008 πŸ› Elsevier Science 🌐 English βš– 694 KB

Ring-opening polymerizations (ROPs) of various cyclic esters [-caprolactone (CL), ␦-valerolactone (VL), rac-lactide (LC)] using a series of Al complexes containing phenoxy-imine ligands of type, Me , have been explored in the presence of n BuOH. Synthesis and identification of 1g and 1h including s