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Activation of carbonyl bonds by quaternary ammoniums and a (Na+:crown-ether) complex: investigation of the ring-opening polymerization of cyclic esters

✍ Scribed by Thomas, Coralie; Milet, Anne; Peruch, Frédéric; Bibal, Brigitte


Book ID
120228233
Publisher
The Royal Society of Chemistry
Year
2013
Tongue
English
Weight
295 KB
Volume
4
Category
Article
ISSN
1759-9954

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✍ Naruhito Iwasa; Michiya Fujiki; Kotohiro Nomura 📂 Article 📅 2008 🏛 Elsevier Science 🌐 English ⚖ 694 KB

Ring-opening polymerizations (ROPs) of various cyclic esters [-caprolactone (CL), ␦-valerolactone (VL), rac-lactide (LC)] using a series of Al complexes containing phenoxy-imine ligands of type, Me , have been explored in the presence of n BuOH. Synthesis and identification of 1g and 1h including s