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Controlled/living ring-opening polymerization of ɛ-caprolactone catalyzed by phosphoric acid

✍ Scribed by ChunXia Chen, Rong Xu, Bin Li

Book ID
113082895
Publisher
SP Science China Press
Year
2012
Tongue
English
Weight
589 KB
Volume
55
Category
Article
ISSN
1674-7291

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Lanthanide Schiff-base complexes with the formula [3,5-tBu 2 -2-(O)C 6 H 2 CH=NC 6 H 5 ] 3 Ln(THF) (Ln = Sc, Y, La, Nd, and Gd) were synthesized by the metathesis reaction of anhydrous LnCl 3 with a Schiff-base sodium salt in good yields (> 80%). The complex containing a neodymium center was charact