Synthesis of poly(norbornene-g-ɛ-caprolactone) copolymers by sequential controlled ring opening polymerization
✍ Scribed by P. Lecomte; D. Mecerreyes; P. Dubois; A. Demonceau; A. F. Noels; R. Jérôme
- Publisher
- Springer
- Year
- 1998
- Tongue
- English
- Weight
- 135 KB
- Volume
- 40
- Category
- Article
- ISSN
- 0170-0839
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📜 SIMILAR VOLUMES
## 3-caprolactone) a b s t r a c t The ring-opening polymerization of 3-caprolactone (CL) was induced by using polypropylene glycol (PPG) as an initiator in the presence of the monomer activator HCl$Et 2 O to synthesize triblock copolymers composed of PPG and poly(3-caprolactone) (PCL). The degree
## Abstract A novel acetylated anhydroglucose oligomer (AGU‐oligomer), prepared by acid catalyzed transglycosidation of potato starch triacetate and ethylene glycol, was used as a multifunctional coinitiator for the ring‐opening polymerization of ε‐caprolactone (ε‐CL). The polymers were synthesized
Lanthanide Schiff-base complexes with the formula [3,5-tBu 2 -2-(O)C 6 H 2 CH=NC 6 H 5 ] 3 Ln(THF) (Ln = Sc, Y, La, Nd, and Gd) were synthesized by the metathesis reaction of anhydrous LnCl 3 with a Schiff-base sodium salt in good yields (> 80%). The complex containing a neodymium center was charact
DSC thermogram of P(DX-b-CL) obtained after a polymerization time of 3.8 h (A) and 39.9 h (B) (see Tab. 2; heating rate: 10 8C/min under N 2 flow, 2 nd scan). much indebted to F.R.I.A. (Fonds pour la Formation a `la Recherche dans l'Industrie et dans l'Agriculture).
## Abstract The new biodegradable chitosan graft copolymer, chitosan‐g‐polycaprolactone, was synthesized by the ring‐opening graft copolymerization of ϵ‐caprolactone onto phthaloyl‐protected chitosan (PHCS) at the hydroxyl group in the presence of tin(II) 2‐ethylhexanoate catalyst via a protection–