Ring-opening polymerization of cyclic ca
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Jyuhou Matsuo; Shinji Nakano; Fumio Sanda; Takeshi Endo
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Article
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1998
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John Wiley and Sons
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English
β 180 KB
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Ring-opening reactions of 1,3-dioxepan-2-one (1) and 1,3-dioxan-2-one (2) with several alcohols were examined. The reactions proceeded without trifluoroacetic acid (TFA) in low conversions, while they proceeded smoothly with TFA to afford the ring-opened adducts and oligomers. Ring-opening polymeriz