## Abstract Tetradentate amineβbis(phenolate) iron(III) halide complexes containing chloro substituents on the aromatic ring are extremely efficient catalysts for controlled radical polymerization. Molecular weights are in good agreement with theoretical values and polydispersity indexes (PDIs) are
Controlled Radical Polymerization Mediated by Cationic Arene Ruthenium Complexes
β Scribed by Tom Opstal; Francis Verpoort
- Book ID
- 106000667
- Publisher
- Springer
- Year
- 2003
- Tongue
- English
- Weight
- 456 KB
- Volume
- 50
- Category
- Article
- ISSN
- 0170-0839
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π SIMILAR VOLUMES
Sparteine was found to be an efficient ligand because when complexed with copper(I) halide it generated a homogeneous catalyst for the atom transfer radical polymerization of styrene or methyl methacrylate, which was initiated by (1-bromoethyl)benzene in the former case and by p-toluenesulfonyl chlo
A series of initiators have been developed for living radical polymerization of methyl methacrylate (MMA) mediated by ruthenium(If) complexes [e.g., RuCI2(PPh3)3; Ph = C6H5]. These initiators include chloromethanes, ~-chloroesters, ct-chloroketones, and cc-bromoesters, among which CCI3COCH3, CHCI2CO