𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Controlled Radical Polymerization Mediated by Amine–Bis(phenolate) Iron(III) Complexes

✍ Scribed by Laura E. N. Allan; Jarret P. MacDonald; Amy M. Reckling; Christopher M. Kozak; Michael P. Shaver

Publisher
John Wiley and Sons
Year
2012
Tongue
English
Weight
485 KB
Volume
33
Category
Article
ISSN
1022-1336

No coin nor oath required. For personal study only.

✦ Synopsis

Abstract

Tetradentate amine–bis(phenolate) iron(III) halide complexes containing chloro substituents on the aromatic ring are extremely efficient catalysts for controlled radical polymerization. Molecular weights are in good agreement with theoretical values and polydispersity indexes (PDIs) are as low as 1.11 for styrene and methyl methacrylate polymerizations. Complexes containing alkyl substituents on the aromatic ring are less efficient. Kinetic data reveal activity for styrene polymerization among the fastest reported to date and initial studies implicate a multimechanism system. Despite the highly colored polymerization media, simple work‐up procedures yield pure white polymers.

📜 SIMILAR VOLUMES

Copolymers Containing Phosphorescent Iri
Copolymers Containing Phosphorescent Iridium(III) Complexes Obtained by Free and Controlled Radical Polymerization Techniques
✍ Christoph Ulbricht; Caglar Remzi Becer; Andreas Winter; Dirk Veldman; Ulrich S. 📂 Article 📅 2008 🏛 John Wiley and Sons 🌐 English ⚖ 558 KB

## Abstract A methacrylate‐functionalized phosphorescent Ir(III)‐complex has been synthesized, characterized, and applied as a monomer in radical copolymerizations. Together with methyl methacrylate, the complex has been copolymerized under free radical polymerization conditions. Aiming for host‐gu

Living Radical Polymerization of Acrylat
Living Radical Polymerization of Acrylates Mediated by 1,3-Bis(2-pyridylimino)isoindolatocobalt(II) Complexes: Monitoring the Chain Growth at the Metal
✍ Björn K. Langlotz; Julio Lloret Fillol; Jürgen H. Gross; Hubert Wadepohl; Lutz H 📂 Article 📅 2008 🏛 John Wiley and Sons 🌐 English ⚖ 629 KB

## Abstract A new type of mediator for cobalt(II)‐mediated radical polymerization is reported which is based on 1,3‐bis(2‐pyridylimino)isoindolate (bpi) as ancillary ligand. The modular synthesis of the bis(pyridylimino)isoindoles (bpiH) employed in this work is based on the condensation of 2‐amino