Block Copolymers by Using Combined Controlled Radical and Radical Promoted Cationic Polymerization Methods
β Scribed by M. Attila Tasdelen; Mustafa Degirmenci; Yusuf Yagci; Oskar Nuyken
- Book ID
- 106000684
- Publisher
- Springer
- Year
- 2003
- Tongue
- English
- Weight
- 321 KB
- Volume
- 50
- Category
- Article
- ISSN
- 0170-0839
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π SIMILAR VOLUMES
## Abstract A new synthetic approach for the preparation of block copolymers by mechanistic transformation from atom transfer radical polymerization (ATRP) to visible lightβinduced free radical promoted cationic polymerization is described. A series of halide endβfunctionalized polystyrenes with di
The homopolymerization of methyl methacrylate (MMA) in the presence of 2,2,6,6-tetramethyl-l-piperidinyloxy (TEMPO) is described and compared to the TEMPO-mediated polymerization of styrene. Furthermore, the formation of block copolymers between MMA and styrene from polystyrene chains with TEMPO fra