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Conjugate addition to 5-phenylsulfinyl 2-substituted 2-cyclopentenones: A new route to 4,5-disubstituted 2-cyclopentenones

โœ Scribed by Manat Pohmakotr; Supatara Popuang


Publisher
Elsevier Science
Year
1988
Tongue
French
Weight
192 KB
Volume
29
Category
Article
ISSN
0040-4039

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Intramolecular acylation of ฮฑ-sulfinyl c
โœ Manat Pohmakotr; Sirirat Chancharunee ๐Ÿ“‚ Article ๐Ÿ“… 1984 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 214 KB

A convenient synthesis of 5-methylene-2-cyclopentenones University, including Methylenomycin B involving the intramolecular acylation of cr-sulfinyl carbanion followed by methylation and pyrolysis is described. 5-Methylene-2-cyclopentenone unit occurs widely in natural products, particularly the cyc