A convenient synthesis of 5-methylene-2-cyclopentenones University, including Methylenomycin B involving the intramolecular acylation of cr-sulfinyl carbanion followed by methylation and pyrolysis is described. 5-Methylene-2-cyclopentenone unit occurs widely in natural products, particularly the cyc
✦ LIBER ✦
Intramolecular acylation of α-sulfinyl carbanion: A new general route to 5-substituted Δ2 cyclopentenones
✍ Scribed by Manat Pohmakotr; Pranee Phinyocheep
- Publisher
- Elsevier Science
- Year
- 1984
- Tongue
- French
- Weight
- 209 KB
- Volume
- 25
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
Intramolecular acylation of α-sulfinyl c
✍
Manat Pohmakotr; Sirirat Chancharunee
📂
Article
📅
1984
🏛
Elsevier Science
🌐
French
⚖ 214 KB
Intramolecular Acylation of α-Sulfinyl C
✍
Manat Pohmakotr; Sirinporn Thamapipol; Patoomratana Tuchinda; Vichai Reutrakul
📂
Article
📅
2007
🏛
John Wiley and Sons
⚖ 27 KB
👁 1 views
A new synthesis of α,β-unsaturated γ- an
✍
Manat Pohmakotr; Prapanpong Jarupan
📂
Article
📅
1985
🏛
Elsevier Science
🌐
French
⚖ 170 KB
Palladium-catalyzed intramolecular allyl
✍
Sophie Vogel; Xavier Bantreil; Guillaume Maitro; Guillaume Prestat; David Madec;
📂
Article
📅
2010
🏛
Elsevier Science
🌐
French
⚖ 484 KB
ChemInform Abstract: A General Strategy
✍
Manat Pohmakotr; Tanasri Bunlaksananusorn; Patoomratana Tuchinda
📂
Article
📅
2010
🏛
John Wiley and Sons
⚖ 37 KB
👁 1 views
Hetero-Diels-Alder cycloadditions of α,β
✍
Jin-Cong Zhuo; Hugo Wyler
📂
Article
📅
1993
🏛
John Wiley and Sons
🌐
German
⚖ 991 KB
## Abstract The [4 + 2] cycloadditions of 2‐oxobut‐3‐enenitrile (1a), 2‐oxopent‐3‐enenitrile (1b), and ethyl 4‐cyano‐4‐oxobut‐2‐enoate (1c) with 1,3‐dimethyluracil (2), 1,3, 6‐trimethyluracil (9), or 1,3,5‐trimethyluracil (16) were investigated. The reactions of 1a with 2 or with 9 lead to bicyclic