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Conjugate addition to the ethylene ketal of 2-carbomethoxy-2-cyclopentenone a synthesis of sarkomycin

✍ Scribed by Alan T. Hewson; David T. MacPherson


Publisher
Elsevier Science
Year
1983
Tongue
French
Weight
102 KB
Volume
24
Category
Article
ISSN
0040-4039

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Theoretical study of the addition of hyd
✍ Carmen Clavero; Miquel Duran; Agustí Lledós; Oscar N. Ventura; Juan Bertrán 📂 Article 📅 1987 🏛 John Wiley and Sons 🌐 English ⚖ 751 KB

The addition of HCl and (HC1)2 to ethylene is theoretically studied by means of a b initio SCF techniques using the 3-21G basis set. A statistical thermodynamics analysis is also carried out. When a comparison is made with the HF and (HF)2 additions to ethylene, the general fact of the catalytic act