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Conformational analysis of the cyclopropylacyl, oxiranylacyl, and aziridinylacyl radicals by electron spin resonance spectroscopy

✍ Scribed by Davies, Alwyn G.; Sutcliffe, Roger

Book ID
121826390
Publisher
Royal Society of Chemistry
Year
1982
Tongue
English
Weight
736 KB
Volume
11
Category
Article
ISSN
1472-779X

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## Abstract The rearrangement of the 2‐methyl‐2‐phenylpropyl (or neophyl) radical **1** to the 1‐methyl‐1‐benzylethyl radical **2** is observed by ESR. spectroscopy during photolysis of di‐__t__‐butylperoxide in __t__‐butylbenzene at 270–360 K. The energy of activation of the rearrangement is deter