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Homolytic rearrangements and the conformations of alkyl radicals by electron spin resonance

✍ Scribed by Edge, D. J.; Kochi, J. K.

Book ID
120240221
Publisher
American Chemical Society
Year
1972
Tongue
English
Weight
856 KB
Volume
94
Category
Article
ISSN
0002-7863

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πŸ“œ SIMILAR VOLUMES

Observation of the Neophyl Radical Rearr
Observation of the Neophyl Radical Rearrangement by Electron Spin Resonance Spectroscopy
✍ Edwin J. Hamilton Jr.; Hanns Fischer πŸ“‚ Article πŸ“… 1973 πŸ› John Wiley and Sons 🌐 German βš– 277 KB

## Abstract The rearrangement of the 2‐methyl‐2‐phenylpropyl (or neophyl) radical **1** to the 1‐methyl‐1‐benzylethyl radical **2** is observed by ESR. spectroscopy during photolysis of di‐__t__‐butylperoxide in __t__‐butylbenzene at 270–360 K. The energy of activation of the rearrangement is deter