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Observation of the Neophyl Radical Rearrangement by Electron Spin Resonance Spectroscopy

✍ Scribed by Edwin J. Hamilton Jr.; Hanns Fischer

Publisher
John Wiley and Sons
Year
1973
Tongue
German
Weight
277 KB
Volume
56
Category
Article
ISSN
0018-019X

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✦ Synopsis

Abstract

The rearrangement of the 2‐methyl‐2‐phenylpropyl (or neophyl) radical 1 to the 1‐methyl‐1‐benzylethyl radical 2 is observed by ESR. spectroscopy during photolysis of di‐t‐butylperoxide in t‐butylbenzene at 270–360 K. The energy of activation of the rearrangement is determined to be (43 ± 9) kJ mol^−1^.

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