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Rearrangements and conformations of chloroalkyl radicals by electron spin resonance

✍ Scribed by Chen, Kuang S.; Tang, David Y. H.; Montgomery, Lawrence K.; Kochi, Jay K.

Book ID: 126880221
Publisher: American Chemical Society
Year: 1974
Tongue: English
Weight: 967 KB
Volume: 96
Category: Article
ISSN: 0002-7863
DOI: 10.1021/ja00814a033

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## Abstract The rearrangement of the 2‐methyl‐2‐phenylpropyl (or neophyl) radical **1** to the 1‐methyl‐1‐benzylethyl radical **2** is observed by ESR. spectroscopy during photolysis of di‐__t__‐butylperoxide in __t__‐butylbenzene at 270–360 K. The energy of activation of the rearrangement is deter