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Conformational Analysis of Chiral Ferrocene–Peptides

✍ Scribed by Katja Heinze; Manuela Beckmann

Publisher
John Wiley and Sons
Year
2005
Tongue
English
Weight
360 KB
Volume
2005
Category
Article
ISSN
1434-1948

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✦ Synopsis

Abstract

Ferrocene‐containing dipeptides Ac‐Fca‐AA‐OMe (AA = L‐Val, L‐Ile) with the artificial amino acid 1'‐aminoferrocene‐1‐carboxylic acid (Fca) and chiral α‐amino acid building blocks display hydrogen‐bonded structures that result in organised helical ferrocene units in solution, as evidenced by spectroscopic and theoretical investigations. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2005)

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