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Condensation reactions involving carbonium ions and Lewis bases in the gas phase. Hydration of the tert-butyl cation

✍ Scribed by Hiraoka, K.; Kebarle, P.


Book ID
127261566
Publisher
American Chemical Society
Year
1977
Tongue
English
Weight
832 KB
Volume
99
Category
Article
ISSN
0002-7863

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UV spectra and kinetics for the reactions of alkyl and alkylperoxy radicals from methyl tert-butyl ether (MTBE) were studied in 1 atm of SF, by the pulse radiolysis-UV absorption technique. UV spectra for the radical mixtures were quantified from 215 to 340 nm. At 240 nm, a, = (2.6 f 0.4) X lo-l8 cm